After Vesper has been kidnapped, Bond speeds away in his Aston Martin from the Hotel Splendide. The car is parked at the Grandhotel Pupp parking lot, the hotel in Karlovy Vary that doubled for Hotel Splendide in the film (also covered earlier). However the parking lot is enclosed by a barrier, which would make it impossible for Bond to speed away from the parking lot as he does in the film.
The hotel has the car park guarded for 24 hours a day. It appears that the more dignifying guests get to park their cars along the road and in the "gun barrel" in front of the hotel.